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Charmander overhears Ash protecting the tail flame to keep him alive. He, Ash and Misty work to save it from wild Pokemon and get it to the Pokemon Center. Brock gets righteously furious on hearing that Charmander's owner abandoned it in the rain.When Pikachu communicates that the weakened, ill Charmander is waiting for his owner, Ash after failing to catch him with a Pokeball decides to respect the Pokemon's wishes.Joe and Giselle becoming friends at the end of "The School of Hard Knocks".In "Challenge of the Samurai", after Metapod evolves into Butterfree, even Misty, who constantly mentioned her hatred of bugs, said it was beautiful.As mentioned above, Ash immediately showed Caterpie off to Misty with immense pride and after Misty bad mouths it, Ash immediately cheers it up and already considers it his friend, marking this moment that Ash doesn't see his Pokemon as pets, but as friends and partners.As soon as Ash caught the two, however, they instantly accepted him as their master and friend. Both Caterpie and Pidgeotto are unusual in that, unlike the games, trainers in the anime usually need to earn the trust of a Pokémon willingly, captured or not.The music that plays in the original Japanese version really sets the mood.You don't even need to understand what they're saying.
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After having spent the entire episode mocking, shocking, and refusing Ash's affection, Pikachu saves him from a flock of Spearow in the middle of a thunderstorm after it sees the lengths Ash will go to protect it from harm (and it realizes that Ash always had the best intentions for it).